Synthesis and reactivity of α-cationic phosphines: the effect of imidazolinium and amidinium substituents.
نویسندگان
چکیده
Mono- and dicationic phosphines have been synthesized through the reaction of chloroimidazolinium or chloroamidinium salts with secondary or primary phosphines respectively. The resulting ligands, which depict a significantly reduced donor ability compared with their neutral analogues, have been used to design Pt(II) and Au(I) complexes that effectively catalyse the hydroarylation of alkynes.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 45 5 شماره
صفحات -
تاریخ انتشار 2016